Bottom-up synthesis of porous coordination frameworks: apical substitution of a pentanuclear tetrahedral precursor.
| Title | Bottom-up synthesis of porous coordination frameworks: apical substitution of a pentanuclear tetrahedral precursor. |
| Publication Type | Journal Article |
| Year of Publication | 2009 |
| Authors | Wang, Xin-Long, Qin Chao, Wu Shui-Xing, Shao Kui-Zhan, Lan Ya-Qian, Wang Shuang, Zhu Dong-Xia, Su Zhong-Min, and Wang En-Bo |
| Journal | Angewandte Chemie (International ed. in English) |
| Volume | 48 |
| Issue | 29 |
| Pagination | 5291-5 |
| Date Published | 2009 |
| Abstract | Top down goes bottom up: A family of microporous interpenetrating diamond frameworks can be constructed from a pentanuclear tetrahedral complex with nitrate groups at the apical positions as an inorganic precursor. A "bottom-up" methodology was used for substitution of the nitrate groups by linear ditopic carboxylate ligands (see picture). The Langmuir surface area of the resulting frameworks is higher than that of classical zeolites. |
| Alternate Journal | Angew. Chem. Int. Ed. Engl. |
| Refereed Designation | Refereed |